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» Soil
Polydimethylsiloxanes (PDMS) degrade when they are added to agricultural or other soils as
a component of sludge. This is a complex process that is initiated by
contact with the clay component of the soil. It is fastest under dry
conditions, but once the silicone molecules are 'unlocked', biological
degradation can follow. Experiments show that the degradation products
may either evaporate into the air or, depending on the soil type, degrade
further in the soil. In either case the ultimate degradation products
are silica and carbon dioxide, thus completing the PDMS life cycle.
A similar mechanism has been shown to operate for VMS during degradation
in the atmosphere.
In view of the significance of the soil compartment in the life cycle of
PDMS, a number of studies have been conducted on various soil-living
animals and plants. For example, there was no evidence of uptake or
adverse effects on worms or crops such as wheat or soybean grown in
sewage sludge amended soils containing PDMS.
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